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Reductive Trimerization of the Trioxo Half‐Sandwich Complex [(η 5 ‐C 5 Me 5 )ReO 3 ] with Deoxygenation: The Electron‐Deficient Cluster Ion [(η 5 ‐C 5 Me 5 ) 3 Re 3 (μ‐O) 6 ] 2+
Author(s) -
Herrmann Wolfgang A.,
Serrano Ricardo,
Ziegler Manfred L.,
Pfisterer Heike,
Nuber Bernd
Publication year - 1985
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198500502
Subject(s) - rhenium , chemistry , cluster (spacecraft) , perrhenate , valence electron , electron , ion , valence (chemistry) , crystallography , deoxygenation , atomic physics , atom (system on chip) , sulfur , inorganic chemistry , catalysis , physics , nuclear physics , computer science , biochemistry , organic chemistry , programming language , embedded system
A novel M 3 O 6 skeletal geometry is shown by the cluster cation of the perrhenate 1 . The six oxygen atoms form a trigonal prism whose three rectangular faces are each symmetrically bridged by a rhenium atom. The cluster cation is, with only 46 valence electrons, an electron‐deficient species.