Dithiocyanogen Reaction without Cleavage of the SS Bond: Cycloaddition with Hexafluoroacetone | Zendy

Roesky Herbert W. | Zendy; Homsy Nayla K. | Zendy; Noltemeyer Mathias | Zendy; Sheldrick George M. | Zendy

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Dithiocyanogen Reaction without Cleavage of the SS Bond: Cycloaddition with Hexafluoroacetone

Author(s) -

Roesky Herbert W.,

Homsy Nayla K.,

Noltemeyer Mathias,

Sheldrick George M.

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198410001

Subject(s) - hexafluoroacetone , cycloaddition , cleavage (geology) , chemistry , derivative (finance) , bond cleavage , diffraction , medicinal chemistry , photochemistry , stereochemistry , organic chemistry , materials science , catalysis , physics , composite material , fracture (geology) , financial economics , optics , economics

Dithiocyanogen 1, a typical pseudohalogen , reacts with hexafluoroacetone 2 in a cycloaddition reaction to give the 4 H ‐dioxazine derivative 3 . In this reaction—other than in reactions of 1 leading to thiocyanates–the SS bond is not cleaved; the structure of 3 was determined by X‐ray diffraction.

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