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A Novel Double‐Stacked Structure in Bis[(oxamide oximato)(oxamide oxime)platinum( II )] [{tris(tetracyanoquinodimethane)}diide], a Molecular Electron Conductor
Author(s) -
Endres Helmut
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198409991
Subject(s) - oxamide , tetracyanoquinodimethane , oxime , ion , chemistry , electron , crystallography , platinum , inorganic chemistry , polymer chemistry , molecule , medicinal chemistry , organic chemistry , physics , quantum mechanics , catalysis
A zig‐zag arrangement of tetracyanoquinodimethane ions (tcnq) 1/2⊖ , as is typical for radical cation stacks of some organic superconductors, is found in the title compound 1 . Perpendicular to the tcnq stacks there are mixed stacks containing two complex cations and an anion tcnq ⊖ . Such mixed stacks occur more often in charge‐transfer complexes rather than as segregated stacks.