Cations of Boron with Coordination Number Three: 1,3,2,4‐Diazadiboretidinium Salts | Zendy

Nöth Heinrich | Zendy; Weber Siegfried | Zendy

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Cations of Boron with Coordination Number Three: 1,3,2,4‐Diazadiboretidinium Salts

Author(s) -

Nöth Heinrich,

Weber Siegfried

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198409941

Subject(s) - borane , moiety , boron , chemistry , halogen , halide , cleavage (geology) , boranes , medicinal chemistry , coordination complex , inorganic chemistry , stereochemistry , organic chemistry , materials science , catalysis , fracture (geology) , composite material , metal , alkyl

The novel cations 3 and 4 containing a diborylamine moiety are isoelectronic with allyl cations and thus likewise extremely stable. 4 is formed directly on rection of the borane 1 with R 2 BBr, while 3 is formed via the intermediate 2 with cleavage of halogen on reaction of 1 with aluminum halide.

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