Synthesis and Characterization of [(C 5 Me 5 )Mn(CO) 2 (SR)]; RS Radicals as Ligands | Zendy

Winter Andreas | Zendy; Huttner Gottfried | Zendy; Zsolnai Laszlo | Zendy; Kroneck Peter | Zendy; Gottlieb Margarete | Zendy

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Synthesis and Characterization of [(C 5 Me 5 )Mn(CO) 2 (SR)]; RS Radicals as Ligands

Author(s) -

Winter Andreas,

Huttner Gottfried,

Zsolnai Laszlo,

Kroneck Peter,

Gottlieb Margarete

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198409751

Subject(s) - unpaired electron , electron paramagnetic resonance , manganese , radical , paramagnetism , characterization (materials science) , oxygen , metal , chemistry , crystallography , photochemistry , inorganic chemistry , materials science , nuclear magnetic resonance , nanotechnology , physics , condensed matter physics , organic chemistry

The deep‐violet paramagnetic manganese complexes 2 can be obtained from 1 by reaction with thioles and oxygen. According to the EPR spectrum of 2a the unpaired electron resides in a MO with highly metallic character. The compounds 2 can be reversibly reduced cyclovoltammetrically.

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