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Synthesis and Characterization of [(C 5 Me 5 )Mn(CO) 2 (SR)]; RS Radicals as Ligands
Author(s) -
Winter Andreas,
Huttner Gottfried,
Zsolnai Laszlo,
Kroneck Peter,
Gottlieb Margarete
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198409751
Subject(s) - unpaired electron , electron paramagnetic resonance , manganese , radical , paramagnetism , characterization (materials science) , oxygen , metal , chemistry , crystallography , photochemistry , inorganic chemistry , materials science , nuclear magnetic resonance , nanotechnology , physics , condensed matter physics , organic chemistry
The deep‐violet paramagnetic manganese complexes 2 can be obtained from 1 by reaction with thioles and oxygen. According to the EPR spectrum of 2a the unpaired electron resides in a MO with highly metallic character. The compounds 2 can be reversibly reduced cyclovoltammetrically.