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The in situ Preparation of 2‐Sulfidophenolate Ligands by Copper‐Catalyzed Oxygen Insertion into Thiophenolates; Crystal Structure of [PPh 4 ] 2 [Mo 2 O 5 (SC 6 H 4 O) 2 ]
Author(s) -
Garner C. David,
Nicholson John R.,
Clegg William
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198409721
Subject(s) - catalysis , in situ , copper , oxygen , chemistry , crystal structure , crystallography , atmospheric oxygen , inorganic chemistry , organic chemistry
2‐Mercaptophenol and its mono‐ and dianions are of interest as intermediate members between pyrocatechol and ortho ‐benzenedithiol. Complex 3 contains SC 6 H 4 O 2⊖ ligands. The in‐situ synthesis of 3 can be achieved by coper‐catalyzed atmospheric oxidation of a 1 :3 mixture of 1 and 2.
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