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Insertion of Platinum into the Sulfur‐Nitrogen Bond of a 1,2,4‐Thiadiazole: Synthesis of a Six‐membered Metallaheterocycle
Author(s) -
Roesky Herbert W.,
Hofmann Hartmut,
Jones Peter G.,
Sheldrick George M.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198409711
Subject(s) - platinum , sulfur , homogeneous , catalysis , chemistry , chelation , nitrogen , combinatorial chemistry , polymer chemistry , stereochemistry , medicinal chemistry , organic chemistry , mathematics , combinatorics
The chelate complex 3 containing a novel C 2 N 2 SPt heterocycle is formed by insertion of Pt at the SN bond of the dinitrile 1 on reaction with the complex 2 . Complexes such as 3 deserve attention, since coordination compounds of platinum find application in homogeneous catalysis and cancer therapy.