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C 4 B 2 H 6 Isomers: Destabilization of the nido ‐Carbaborane Structure by Amino Substituents and a Novel Classical Isomer
Author(s) -
Herberich Gerhard E.,
Ohst Holger,
Mayer Horst
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198409691
Subject(s) - chemistry , substitution (logic) , derivative (finance) , stereochemistry , computational chemistry , computer science , financial economics , economics , programming language
Classical and non‐classical derivatives of C 4 B 2 H 6 can be synthesized from the borole dianion 1 . Depending upon the pattern of substitution, either the classical 2,6‐diboroabicyclo[3.1.0]hex‐3‐ene derivative 2 or the non‐classical nido ‐carbaborane 3 is the more stable.