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Di‐(μ‐amido)dirhodium Complexes: Structure of [Rh 2 (μ‐(NH) 2 naphth)I 2 (CO) 2 (PPh 3 ) 2 ]
Author(s) -
Oro Luis A.,
Fernández Maria J.,
Modrego Javier,
FocesFoces Concha,
Cano Felix H.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198409131
Subject(s) - deprotonation , chemistry , ligand (biochemistry) , medicinal chemistry , bridging ligand , stereochemistry , crystallography , crystal structure , organic chemistry , ion , receptor , biochemistry
A Novel class of binuclear amido complexes containing doubly deprotonated 1,8‐diaminonaphthalene as a bridging bisdihapto ligand has now been synthesized. The title compound is formed by successive reaction of [Rh(acac)(CO) 2 ] with 1,8‐C 10 H 6 (NH 2 ) 2 , PPh 3 and I 2 , whereby all intermediates have been isolated.