Premium
Isocyanide Insertion into a Uranium‐Carbon Double Bond
Author(s) -
Cramer Roger E.,
Panchanatheswaran K.,
Gilje John W.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198409121
Subject(s) - isocyanide , yield (engineering) , uranium , inert gas , chemistry , carbon fibers , inert , double bond , insertion reaction , metal , reinforced carbon–carbon , polymer chemistry , stereochemistry , materials science , organic chemistry , metallurgy , catalysis , composite number , composite material
The red crystalline azauranacyclopropene 3 —stable for months under an inert gas or in vacuo—is formed in 53% yield on reaction of the carbeneuranium complex 1 with cyclohexyl isocyanide 2 . Compound 3 is the first completely characterized product of insertion of an isocyanide into a metal‐carbon double bond.