Isocyanide Insertion into a Uranium‐Carbon Double Bond | Zendy

Cramer Roger E. | Zendy; Panchanatheswaran K. | Zendy; Gilje John W. | Zendy

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Isocyanide Insertion into a Uranium‐Carbon Double Bond

Author(s) -

Cramer Roger E.,

Panchanatheswaran K.,

Gilje John W.

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198409121

Subject(s) - isocyanide , yield (engineering) , uranium , inert gas , chemistry , carbon fibers , inert , double bond , insertion reaction , metal , reinforced carbon–carbon , polymer chemistry , stereochemistry , materials science , organic chemistry , metallurgy , catalysis , composite number , composite material

The red crystalline azauranacyclopropene 3 —stable for months under an inert gas or in vacuo—is formed in 53% yield on reaction of the carbeneuranium complex 1 with cyclohexyl isocyanide 2 . Compound 3 is the first completely characterized product of insertion of an isocyanide into a metal‐carbon double bond.

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