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Macrobicyclic Polyethers as V‐Shaped Hosts for cis ‐Diammine‐Transition Metal Complexes
Author(s) -
Alston David R.,
Slawin Alexandra M. Z.,
Stoddart J. Fraser,
Williams David J.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198408211
Subject(s) - transition metal , adduct , chemistry , benzene , metal , stereochemistry , polymer chemistry , crystallography , medicinal chemistry , organic chemistry , catalysis
Ligands of type 1 with three polyether chains between two benzene rings were specifically designed to coordinate cis ‐diammine complexes such as [Rh(cod)(NH 3 ) 2 ][PF 6 ]. 1 , X OCH 2 CH 2 O, O‐ o ‐C 6 H 4 O, etc. does, in fact, form 1:1 adducts with the Rh‐complex, both in solution are mainly held together by H bridges.
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