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[(CO) 3 PPh 3 FeCN i Pr 2 ] ⊕ , a Novel Stable Carbyneiron Complex Cation
Author(s) -
Fischer Ernst Otto,
Schneider Johannes,
Neugebauer Dietmar
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198408201
Subject(s) - carbyne , carbene , chemistry , crystallography , stereochemistry , organic chemistry , catalysis
A cation with FeC bonding is contained in the isolable carbyne complex 2 , which was prepared from the carbene complex 1 and BCl 3 and characterized by X‐ray structure analysis. 1 , with PPh 3 replaced by CO, does not react in an analogous fashion with BCl 3 .