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(PMe 3 ) 3 MS 7 (M = Ru, Os): The First Polysulfido Metal Complexes with a Tridentate S2 n n⊖ Ligand
Author(s) -
Gotzig Josef,
Rheingold Arnold L.,
Werner Helmut
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198408141
Subject(s) - ligand (biochemistry) , metal , chemistry , crystallography , ruthenium , inorganic chemistry , catalysis , organic chemistry , receptor , biochemistry
An Ms 7 bicycle has been surprisingly obtained from the Ru‐ and Os‐complexes 1 . Reaction of 1 with S 8 leads to formation of the MS 6 species 2 . On attempting to grow single crystals of 2 , it was converted into the MS 7 ‐analogue 3 (X‐ray structure analysis).
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