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A Facile Route to 1,4,7‐Trithiacyclononane
Author(s) -
Sellmann Dieter,
Zapf Lothar
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198408071
Subject(s) - alkylation , yield (engineering) , molybdenum , combinatorial chemistry , chemistry , materials science , nanotechnology , organic chemistry , catalysis , metallurgy
An increase from 4% to 60% in the yield of 1,4,7‐trithiacyclononane is achieved by a new synthetic method. The key step is the “template” alkylation of 1 with 1,2‐dibromoethane at the molybdenum(0) center.