Conversion of “LiNS(F)OCMe 3 ” into an (Li 8 ) 2  Double Cluster | Zendy

Isenberg Wilhelm | Zendy; Mews Rüdiger | Zendy; Sheldrick George M. | Zendy

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Conversion of “LiNS(F)OCMe 3 ” into an (Li 8 ) 2 Double Cluster

Author(s) -

Isenberg Wilhelm,

Mews Rüdiger,

Sheldrick George M.

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198407951

Subject(s) - nucleophile , cluster (spacecraft) , chemistry , molar ratio , nucleophilic addition , adduct , computational chemistry , crystallography , organic chemistry , catalysis , computer science , programming language

Nucleophilic substitutions of thiazyl fluoride (NSF) should afford access to thiazyl derivatives RSN. On reaction of NSF with LiOCMe 3 , the primary product “LiNS(F)OCMe 3 ” could be trapped for the first time as the double cluster 1 and subsequently characterized. A molar ratio of NSF: nucleophile of 1:1 is essential for the formation of 1 .

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