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Conversion of “LiNS(F)OCMe 3 ” into an (Li 8 ) 2 Double Cluster
Author(s) -
Isenberg Wilhelm,
Mews Rüdiger,
Sheldrick George M.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198407951
Subject(s) - nucleophile , cluster (spacecraft) , chemistry , molar ratio , nucleophilic addition , adduct , computational chemistry , crystallography , organic chemistry , catalysis , computer science , programming language
Nucleophilic substitutions of thiazyl fluoride (NSF) should afford access to thiazyl derivatives RSN. On reaction of NSF with LiOCMe 3 , the primary product “LiNS(F)OCMe 3 ” could be trapped for the first time as the double cluster 1 and subsequently characterized. A molar ratio of NSF: nucleophile of 1:1 is essential for the formation of 1 .