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Facile Synthesis of PhAsAsPh Complexes
Author(s) -
Huttner Gottfried,
Jibril Ibrahim
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198407401
Subject(s) - dehydrogenation , chemistry , stereochemistry , combinatorial chemistry , catalysis , organic chemistry
The dehydrogenation of complexed diphenyldiarsanes 1 to complexes with “arsenobenzene” ligands (with Pd/C or Pt/C) constitutes a suitable route to this otherwise difficultly accessible class of compounds. X‐ray structure analyses have been carried out on 2 , L P(OMe) 3 or 2L bpy, as well as 2 , Cr(CO) 4 P(OMe) 3 instead of PdL 2 .