Synthesis, Structure, and Reactions of Cluster‐Stabilized Phosphaalkenes | Zendy

Knoll Konrad | Zendy; Huttner Gottfried | Zendy; Wasiucionek Marek | Zendy; Zsolnai Laszlo | Zendy

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Synthesis, Structure, and Reactions of Cluster‐Stabilized Phosphaalkenes

Author(s) -

Knoll Konrad,

Huttner Gottfried,

Wasiucionek Marek,

Zsolnai Laszlo

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198407391

Subject(s) - cluster (spacecraft) , ligand (biochemistry) , chemistry , bridge (graph theory) , stereochemistry , crystallography , computer science , receptor , biochemistry , medicine , programming language

The transformation of a cluster with a μ 3 ‐phosphanediyl ligand into the title compound 1 , R p ‐H 3 COC 6 H 4 , was achieved by reaction with NaNH 2 and CH 2 I 2 . In 1 , a phosphaalkene RPCH 2 is stabilized for the first time as a μ 3 ‐η 2 ‐bridge; it can be reduced in the cluster to a novel type of μ 3 ‐η 3 ‐phosphino ligand RPCH 3 .

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