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Novel Synthesis of Complexes with Metal‐Phosphorus Double Bonds
Author(s) -
Gross Elisabeth,
Jörg Klaus,
Fiederling Klaus,
Göttlein Axel,
Malisch Wolfgang,
Boese Roland
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198407381
Subject(s) - dehydrohalogenation , phosphorus , deamination , chemistry , metal , base (topology) , medicinal chemistry , inorganic chemistry , stereochemistry , polymer chemistry , organic chemistry , mathematics , catalysis , mathematical analysis , enzyme
The mild preparation of Mo P‐ and W P‐compounds has been achieved by base‐assisted dehydrohalogenation or deamination of phosphanes: M(X)P(Y)→MP + XY.The compound 2 , R H, obtained from 1 by this reaction principle, can be converted in a controlled way into metallacycles of the type 3 (X) S, CH 2 , Fe(CO) 4 .
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