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Stable Formylmanganese Complexes
Author(s) -
Berke Heinz,
Huttner Gottfried,
Scheidsteger Olaf,
Weiler Gertrud
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198407351
Subject(s) - chemistry , catalysis , transition metal , homogeneous , aryl , medicinal chemistry , metal , stereochemistry , organic chemistry , physics , alkyl , thermodynamics
The first stable neutral formyl complexes of a light transition metal , the title compounds 2 with aryl phosphite ligands, were prepared by reduction of the cations of 1 . Formyl complexes have been postulated as intermediates in the homogeneous catalytic hydrogenation of CO (L P(OPh) 3 , L′ CO; L P( o ‐OTolyl) 3 , L′ CO; L L′ P(OPh) 3 ).
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