Premium
Facile Synthesis of Highly Reactive Ferracycloalkanes
Author(s) -
Lindner Ekkehard,
Schauss Eckard,
Hiller Wolfgang,
Fawzi Riad
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198407111
Subject(s) - cycloaddition , reactive intermediate , chemistry , nucleophile , combinatorial chemistry , enantiomer , nucleophilic addition , catalysis , metal , stereochemistry , organic chemistry
Nucleophilic elimination‐cycloaddition is a suitable method for the synthesis of cyclic organoiron compounds. 2a , L CO, is extremely volatile. In the case of the more stable 2b , L PPh 3 , enantiomers have been found in the crystal. 3a , L CO (already known), and 3b , L PPh 3 , are likewise readily accessible in this way.—Metallacyclopentanes such as 2 occur as highly reactive intermediates in numerous metal‐catalyzed reactions.