Facile Synthesis of Highly Reactive Ferracycloalkanes | Zendy

Lindner Ekkehard | Zendy; Schauss Eckard | Zendy; Hiller Wolfgang | Zendy; Fawzi Riad | Zendy

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Facile Synthesis of Highly Reactive Ferracycloalkanes

Author(s) -

Lindner Ekkehard,

Schauss Eckard,

Hiller Wolfgang,

Fawzi Riad

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198407111

Subject(s) - cycloaddition , reactive intermediate , chemistry , nucleophile , combinatorial chemistry , enantiomer , nucleophilic addition , catalysis , metal , stereochemistry , organic chemistry

Nucleophilic elimination‐cycloaddition is a suitable method for the synthesis of cyclic organoiron compounds. 2a , L CO, is extremely volatile. In the case of the more stable 2b , L PPh 3 , enantiomers have been found in the crystal. 3a , L CO (already known), and 3b , L PPh 3 , are likewise readily accessible in this way.—Metallacyclopentanes such as 2 occur as highly reactive intermediates in numerous metal‐catalyzed reactions.

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