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Novel Tricarbonyl(η 4 ‐dihydroacepentalene)iron Complexes and Tricarbonyl(η 2 ‐dihydroacepentalene)ferrates(−2)
Author(s) -
Butenschön Holger,
de Meijere Armin
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198407071
Subject(s) - chemistry , olefin fiber , medicinal chemistry , spectroscopy , ion , inorganic chemistry , catalysis , organic chemistry , physics , quantum mechanics
The first spectroscopically characterized (η 2 ‐olefin)ferrates( – 2), 3 , are formed on reduction of the novel (η 4 ‐diene)iron complexes 2 with sodium. This reaction proceeds via a radical anion; high spin density at the iron is detected by ESR spectroscopy in the case of the reduction product of 2 , NR 2 = piperidino.
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