Isoelectronic Radical Ions from Single‐Electron Transfer Reactions: Direct Observation of Persistent Solvent‐Separated Radical Anion/Radical Cation Pairs | Zendy

Kaim Wolfgang | Zendy

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Isoelectronic Radical Ions from Single‐Electron Transfer Reactions: Direct Observation of Persistent Solvent‐Separated Radical Anion/Radical Cation Pairs

Author(s) -

Kaim Wolfgang

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198406131

Subject(s) - chemistry , radical ion , steric effects , electron transfer , ion , photochemistry , solvent , electron acceptor , acceptor , electron , organic chemistry , quantum mechanics , condensed matter physics , physics

Simultaneous generation of persistent radical anions and radical cations following single‐electron transfer — an unusual phenomenon for organic compounds of main group metals — is facilitated by using electron‐rich and sterically hindered donors 1 . Compound 2 , for example, functions as an acceptor.

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