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Selective Synthesis of Carbonyl Olefinating or Alkylating Reagents from MoCl 5 and MeLi by Changing the Solvent or the Rate of Addition of MeLi
Author(s) -
Kauffmann Thomas,
Kieper Gudrun
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198405321
Subject(s) - reagent , tetrahydrofuran , solvent , chemistry , organic solvent , medicinal chemistry , organic chemistry , chemical engineering , engineering
The simple change from rapid to slow admixture of the educts is decisive in determining whether carbonyl olefinating reagents (1, 2) + CH 4 or carbonyl alkylating reagents ( 3, 4 ) + ethane are formed from MoCl 5 and MeLi in tetrahydrofuran.