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Pentamethylcyclopentadienyllutetium Derivatives of Dimethylphosphoniobis(methanide)
Author(s) -
Schumann Herbert,
Albrecht Ilse,
Reier FriedrichWilhelm,
Hahn Ekkehardt
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198405221
Subject(s) - lutetium , ylide , derivative (finance) , moisture , lanthanide , phosphorus , medicinal chemistry , chemistry , nuclear chemistry , physics , organic chemistry , ion , economics , financial economics , yttrium , oxide
The first X‐ray structure analysis of a lanthanoid‐phosphorus ylide complex has been carried out on the lutetium derivative 1 . Compound 1 , which is extremely sensitive to air and moisture, was synthesized from (C 5 Me 5 ) 2 LuCl 2 Na(Et 2 O) 2 and Li(CH 2 ) 2 P(CH 3 ) 2 .