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[Cu 6 I 11 ] 5⊖ —a Polyanion with Trigonal‐Prismatic Arrangement of Six Metal Atoms
Author(s) -
MahdjourHassanAbadi Farbod,
Hartl Hans,
Fuchs Joachim
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198405141
Subject(s) - trigonal crystal system , trigonal prismatic molecular geometry , trigonal pyramidal molecular geometry , copper , crystallography , metal , ion , iodine , prism , materials science , chemistry , crystal structure , physics , octahedron , metallurgy , optics , organic chemistry
A rare arrangement of metal atoms, previously not observed in copper compounds , occurs in the iodocuprate(I) ion in [Cu 6 I 11 ] 5⊖ . The Cu atoms form a trigonal prism to whose six edges and five faces the eleven iodine atoms are bonded.