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First Evidence for an Intermediate Nitrilo‐λ 5 ‐phosphane
Author(s) -
Sicard Ghislaine,
Baceiredo Antoine,
Bertrand Guy,
Majoral JeanPierre
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198404591
Subject(s) - chemistry
( i Pr 2 N) 2 PN—a nitrene or a nitrile analogue? As suggested by ab initio calculations on H 2 PN, the intermediate compound 2 , obtained from azide 1 , proves to be a “nitrile” in trapping reactions.
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