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Photochemical Generation of Triphenylsilylboranediyl (C 6 H 5 ) 3 SiB: from Organosilylboranes
Author(s) -
Pachaly Bernd,
West Robert
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198404541
Subject(s) - nitrene , photodissociation , carbene , boron , yield (engineering) , chemistry , photochemistry , boro , crystallography , materials science , organic chemistry , catalysis , metallurgy
A carbene‐ or nitrene‐analogous boron species , the title compound 1 , was generated by photolysis of RB(SiPh 3 ) 2 or B(SiPh 3 ) 3 and detected by trapping reactions. 1 inserts into CH and CO bonds and cycloadds to CC bonds to yield borirenes such as 2 .
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