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Oxidation with Palladium Salts: Catalytic Preparation of Allyl Acetates from Monoolefins Using a Three‐Component Oxidation System
Author(s) -
Heumann Andreas,
Åkermark Björn
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198404531
Subject(s) - yield (engineering) , catalysis , palladium , chemistry , component (thermodynamics) , organic chemistry , polymer chemistry , materials science , physics , metallurgy , thermodynamics
The selective conversion of monoolefins into allyl acetates can be achieved using a novel catalyst system. Reaction 1 → 2 (up to 95% yield) exemplifies this. Other cycloalkenes afford 60–90% yield, while open‐chain alkenes can give rise to isomers.