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Crystal Structure and Conductivity of a Novel Charge‐Transfer Complex of N,N ′‐Dicyano‐1,4‐naphthoquinonediimine and Tetrathiafulvalene
Author(s) -
Aumüller Alexander,
Hädicke Erich,
Hünig Siegfried,
Schätzle Albin,
von Schütz Jost Ulrich
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198404491
Subject(s) - tetrathiafulvalene , analogy , conductivity , charge (physics) , crystal structure , charge transfer complex , electrical resistivity and conductivity , crystallography , crystal (programming language) , materials science , chemistry , molecule , physics , computer science , photochemistry , quantum mechanics , organic chemistry , philosophy , linguistics , programming language
The structural analogy between N,N ′‐dicyanoquinonediimines, such as 1, and tetracyanoquinodimethanes suggests that it should be possible to prepare CT‐complexes from 1 and the “standard donor” 2 . The complex formed from 1 and 2 (X‐ray structure analysis) is, in fact, characterized by electrical conductivity.