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Ligand Extrusion from the As 4 S 4 ‐Cage by [C 5 Me 5 (CO) 2 Mo] 2 : Formation of (C 5 Me 5 ) 2 Mo 2 (CO) 4 (μ,η 2 ‐As 2 ), C 5 Me 5 (CO) 2 Mo(η 3 ‐As 3 ), and (C 5 Me 5 ) 2 Mo 2 As 2 S 3
Author(s) -
Bernal Ivan,
Brunner Henri,
Meier Walter,
Pfisterer Heike,
Wachter Joachim,
Ziegler Manfred L.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198404381
Subject(s) - ligand (biochemistry) , derivative (finance) , cage , chemistry , extrusion , crystallography , stereochemistry , materials science , mathematics , combinatorics , metallurgy , biochemistry , receptor , financial economics , economics
Three unusual complexes —inter alia the first complex with an AsS ligand and a monosubstituted derivative of yellow arsenic—were obtained via the previously unknown title reaction of realgar.