Premium
[Mo 4 (μ 3 ‐S) 4 (μ‐S 2 CNEt 2 ) 2 (S 2 CNEt 2 ) 4 ], a Compound Containing a Cubane‐Like Mo 4 S 4 Cluster
Author(s) -
Mak Thomas C. W.,
Jasim Khalid S.,
Chieh Chung
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198403911
Subject(s) - dithiocarbamate , molybdenum , tetrahedron , crystallography , bond length , octahedron , chemistry , stereochemistry , crystal structure , inorganic chemistry , organic chemistry
An Mo 4 tetrahedron as part of a readily distorted Mo 4 S 4 cube is observed in the title compound (black crystals). In this complex, molybdenum is coordinated only by sulfur. Four of the six dithiocarbamate ligands are each bound to an Mo atom; the two remaining ligands each bridge an MoMo bond.