Premium
Stepwise Hydrogenation of Benzonitrile on a Ru 3 ‐Cluster
Author(s) -
Bernhardt Wolfgang,
Vahrenkamp Heinrich
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198403811
Subject(s) - benzonitrile , catalysis , cluster (spacecraft) , chemistry , atmospheric pressure , inorganic chemistry , medicinal chemistry , organic chemistry , meteorology , physics , computer science , programming language
Two products of the reduction of PhCN on Ru 3 (CO) 12 with H 2 at atmospheric pressure have been isolated and characterized: the PhCHNH and PhCH 2 NH 2 ‐complexes 1 and 2 , respectively. This reaction demonstrates the validity of the concept of using clusters as models for catalyst surfaces.