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Synthesis and Structure of a 1,3‐Dihydro‐1,3‐diborete
Author(s) -
Hildenbrand Manfred,
Pritzkow Hans,
Zenneck Ulrich,
Siebert Walter
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198403711
Subject(s) - ring (chemistry) , halogenation , planar , skeleton (computer programming) , chemistry , crystallography , stereochemistry , computer science , organic chemistry , computer graphics (images) , programming language
A non‐planar B 2 C 2 skeleton is present in the title compound 2 , which was prepared by dehalogenation of the 1,2‐diborylethene 1 . An X‐ray structure analysis showed that the ring CB bonds are quite short that the distance between the ring C‐atoms is 1.81 Å (R 1 Me 2 N, R 2 t Bu)