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Detection of Intramolecular Linkage Isomerization of a (Pseudo)tetrahedral Nickel( II ) Bis(chelate)
Author(s) -
Knorr Rudolf,
Ruf Friedrich
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198403681
Subject(s) - isomerization , intramolecular force , nickel , chemistry , kinetics , chelation , linkage isomerism , linkage (software) , stereochemistry , crystallography , catalysis , metal , inorganic chemistry , organic chemistry , physics , biochemistry , quantum mechanics , gene
The “interchange” between the six almost equivalent N ‐ substituents in the complex 1 leads to an equilibrium of species with two (= 1), one, or no exocyclic tolyl group. The kinetics of this isomerization, which has been studied in detail, begins with the monomolecular rupture of the N 5 Ni bond.