Detection of Intramolecular Linkage Isomerization of a (Pseudo)tetrahedral Nickel( II ) Bis(chelate) | Zendy

Knorr Rudolf | Zendy; Ruf Friedrich | Zendy

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Detection of Intramolecular Linkage Isomerization of a (Pseudo)tetrahedral Nickel( II ) Bis(chelate)

Author(s) -

Knorr Rudolf,

Ruf Friedrich

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198403681

Subject(s) - isomerization , intramolecular force , nickel , chemistry , kinetics , chelation , linkage isomerism , linkage (software) , stereochemistry , crystallography , catalysis , metal , inorganic chemistry , organic chemistry , physics , biochemistry , quantum mechanics , gene

The “interchange” between the six almost equivalent N ‐ substituents in the complex 1 leads to an equilibrium of species with two (= 1), one, or no exocyclic tolyl group. The kinetics of this isomerization, which has been studied in detail, begins with the monomolecular rupture of the N 5 Ni bond.

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