Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO 6 Ni 2 C 2 (Co) 16 ] 2− | Zendy

Arrigoni Aurora | Zendy; Ceriotti Alessandro | Zendy; Pergola Roberto Della | Zendy; Longoni Giuliano | Zendy; Manassero Mario | Zendy; Masciocchi Norberto | Zendy; Sansoni Mirella | Zendy

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Synthesis and Crystal Structure of the Dicarbido Bimetallic Cluster [CO 6 Ni 2 C 2 (Co) 16 ] 2−

Author(s) -

Arrigoni Aurora,

Ceriotti Alessandro,

Pergola Roberto Della,

Longoni Giuliano,

Manassero Mario,

Masciocchi Norberto,

Sansoni Mirella

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198403221

Subject(s) - delocalized electron , cluster (spacecraft) , bimetallic strip , crystallography , valence electron , electron counting , electron delocalization , crystal structure , valence (chemistry) , atomic physics , chemistry , electron , materials science , physics , metal , nuclear physics , organic chemistry , computer science , programming language

In the title compound two C‐atoms are located in the cavity of a cluster . The CċC distance in very short—only 1.49 Å (for comparison: CC single bond 1.54 Å)—but, as deduced from a consideration of the number of cluster valence electrons, a delocalized CC interaction is more probable than a localized one.

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