Methyl(thioxo)phosphane: Generation and Trapping Reaction with Mn 2 (CO) 10 | Zendy

Lindner Ekkehard | Zendy; Auch Konrad | Zendy; Hiller Wolfgang | Zendy; Fawzi Riad | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Methyl(thioxo)phosphane: Generation and Trapping Reaction with Mn 2 (CO) 10

Author(s) -

Lindner Ekkehard,

Auch Konrad,

Hiller Wolfgang,

Fawzi Riad

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198403201

Subject(s) - chemistry , halogenation , phosphorane , ligand (biochemistry) , trapping , atom (system on chip) , magnesium , manganese , medicinal chemistry , crystallography , organic chemistry , receptor , ecology , biochemistry , computer science , embedded system , biology

H 3 CPS, the first organophosphorus species with a P III S double bond , could be generated as intermediate by dehalogenation of the phosphorane H 3 CP(S)Cl 2 with highly reactive magnesium. It was trapped with Mn 2 (CO) 10 . The H 3 CPS ligand in complex 1 is coupled side‐on with Mn(CO) 4 and end‐on via the P atom with Mn(CO) 5 .

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research