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Methyl(thioxo)phosphane: Generation and Trapping Reaction with Mn 2 (CO) 10
Author(s) -
Lindner Ekkehard,
Auch Konrad,
Hiller Wolfgang,
Fawzi Riad
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198403201
Subject(s) - chemistry , halogenation , phosphorane , ligand (biochemistry) , trapping , atom (system on chip) , magnesium , manganese , medicinal chemistry , crystallography , organic chemistry , receptor , ecology , biochemistry , computer science , embedded system , biology
H 3 CPS, the first organophosphorus species with a P III S double bond , could be generated as intermediate by dehalogenation of the phosphorane H 3 CP(S)Cl 2 with highly reactive magnesium. It was trapped with Mn 2 (CO) 10 . The H 3 CPS ligand in complex 1 is coupled side‐on with Mn(CO) 4 and end‐on via the P atom with Mn(CO) 5 .