Chiral Electron Transfer Compounds: Binaphtho[2,3‐ a ]azulenequinone and Binaphtho[2,3‐ a ]azulenehydroquinone Derivatives by Oxidative Coupling | Zendy

Bindl Johann | Zendy; Pilidis Georgios | Zendy; Daub Jörg | Zendy

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Chiral Electron Transfer Compounds: Binaphtho[2,3‐ a ]azulenequinone and Binaphtho[2,3‐ a ]azulenehydroquinone Derivatives by Oxidative Coupling

Author(s) -

Bindl Johann,

Pilidis Georgios,

Daub Jörg

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198403141

Subject(s) - oxidative coupling of methane , oxidative phosphorylation , electron transfer , coupling (piping) , chemistry , electron , computational chemistry , physics , photochemistry , materials science , organic chemistry , quantum mechanics , catalysis , biochemistry , metallurgy

Novel quinonoid‐hydroquinonoid compounds —the binaphthoazulene derivatives 1 —could be prepared from the corresponding dialkoxynaphthoazulenes. The compounds 1 reveal a structure‐specific rotameric equilibrium. 1a is obtained as a diastereomeric mixture (65:35, 30% de ).

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