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Chiral Electron Transfer Compounds: Binaphtho[2,3‐ a ]azulenequinone and Binaphtho[2,3‐ a ]azulenehydroquinone Derivatives by Oxidative Coupling
Author(s) -
Bindl Johann,
Pilidis Georgios,
Daub Jörg
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198403141
Subject(s) - oxidative coupling of methane , oxidative phosphorylation , electron transfer , coupling (piping) , chemistry , electron , computational chemistry , physics , photochemistry , materials science , organic chemistry , quantum mechanics , catalysis , biochemistry , metallurgy
Novel quinonoid‐hydroquinonoid compounds —the binaphthoazulene derivatives 1 —could be prepared from the corresponding dialkoxynaphthoazulenes. The compounds 1 reveal a structure‐specific rotameric equilibrium. 1a is obtained as a diastereomeric mixture (65:35, 30% de ).