[Cu 12 S 8 ] 4⊖ : A Closed Binary Copper( I ) Sulfide Cage with Cuboctahedral Metal and Cubic Sulfur Arrangements | Zendy

Betz Peter | Zendy; Krebs Bernt | Zendy; Henkel Gerald | Zendy

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[Cu 12 S 8 ] 4⊖ : A Closed Binary Copper( I ) Sulfide Cage with Cuboctahedral Metal and Cubic Sulfur Arrangements

Author(s) -

Betz Peter,

Krebs Bernt,

Henkel Gerald

Publication year - 1984

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198403111

Subject(s) - copper , sulfur , copper sulfide , metal , sulfide , cluster (spacecraft) , cage , crystallography , chemistry , inorganic chemistry , binary number , materials science , metallurgy , mathematics , arithmetic , combinatorics , computer science , programming language

As the largest CuS cluster known to date , [Cu 12 S 8 ] 4⊖ occupies a special position. It is the first copper( I ) complex containing exclusively sulfidic ligands that has been isolated. The Ph 4 P salt is formed on reaction of CuCl 2 ·2H 2 O with EtS ⊖ and Li 2 S in the presence of Ph 4 PBr.

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