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Synthesis of the First Pt‐Au Cluster by an Unexpected H ⊕ ‐Substitution at trans ‐PtH(Cl)L 2
Author(s) -
Braunstein Pierre,
Lehner Hans,
Matt Dominique,
Tiripicchio Antonio,
TiripicchioCamellini Marisa
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198403041
Subject(s) - substitution (logic) , isosceles triangle , chemistry , cluster (spacecraft) , crystallography , unit (ring theory) , stereochemistry , medicinal chemistry , mathematics , geometry , computer science , mathematics education , programming language
In a novel type of exchange reactions at monohydridoplatinum complexes trans ‐PtH(Cl)L 2 (L=phosphane), H ⊕ is replaced by Au 2 L 2 . 1 is the first compound containing PtAu bonds. The PtAu 2 unit forms an isosceles triangle.
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