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Reactions of Diphenyl(trimethylsilyl)phosphane with Alkyl(pentacarbonyl)manganese; Synthesis of the Ylide Complexes and a New Driving Force for CO Insertion
Author(s) -
Vaughn George D.,
Krein K. Alex,
Gladysz John A.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198402451
Subject(s) - ylide , alkyl , insertion reaction , chemistry , trimethylsilyl , manganese , photochemistry , medicinal chemistry , organic chemistry , catalysis
Promotion of CO‐insertion into metal‐alkyl bonds is of current interest. A novel possibility is provided by the use of the silylphosphane 1 : The CO‐insertion is assisted by formation of the SiO bond. This reaction opens up access to the ylide complexes 3 .
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