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Dilithiomethylenecyclohexane — A Stable 1,1‐Dilithioalkene
Author(s) -
Maercker Adalbert,
Dujardin Ralf
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198402241
Subject(s) - double bond , ground state , state (computer science) , chemistry , crystallography , materials science , computational chemistry , pure mathematics , mathematics , physics , atomic physics , polymer chemistry , algorithm
The first compounds containing the part‐structurecould be obtained from the corresponding t BuHg compounds and t BuLi. 1 and 2 , which should have an orthogonal “double bond” and a triplet ground state, are stable but insoluble.