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Sn 3 (N t Bu) 2 (O t Bu) 2 , A Molecule with a Novel, Heptaatomic, Polycyclic Framework
Author(s) -
Veith Michael,
Frank Walter
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198401581
Subject(s) - trigonal crystal system , molecule , product (mathematics) , crystallography , physics , chemistry , stereochemistry , crystal structure , mathematics , geometry , organic chemistry
The novel polycycle Sn 3 N 2 O 2 is adopted by the framework of the product 1 , which is stable up to 250°C and is obtained by reaction of Me 2 Si(N t Bu) 3 Sn 2 with Sn(O t Bu) 2 . 1 is formed formally by “fusing” two trigonal SnN 2 OSn bipyramids at an SnN 2 face.