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Synthesis and Structure of a Five‐Coordinate Manganese( I ) Complex
Author(s) -
Scherer Otto J.,
Kerth Jürgen,
Sheldrick William S.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198401561
Subject(s) - manganese , crystal structure , square pyramidal molecular geometry , crystallography , chemistry , organic chemistry
The 16‐electron manganese( I ) complex 1 , with five ligands is astonishingly stable: It can even be handled for short periods of time in air! Crystal structure analysis of 1 establishes that the manganese has a distorted, square‐pyramidal environment.