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Cyclic Carboxylic Acid‐Organoboron Compounds with BHB Bridge Bonding
Author(s) -
Idelmann Peter,
Müller Gerhard,
Scheidt Walter R.,
Schüssler Wilhelm,
Köster Roland,
Seevogel K.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198401531
Subject(s) - pivalic acid , boranes , ring (chemistry) , carboxylic acid , chemistry , nonane , bridge (graph theory) , medicinal chemistry , organic chemistry , boron , catalysis , medicine
An almost planar six‐membered ring with 3c2e BHB bonding is formed as the product 1 of the reaction between pivalic acid and the diorganohydrorane 2 (9‐borabicyclo[3.3.1]nonane, 9‐BBN). Compounds such as 1 are allegedly intermediates in the reduction of carboxylic acids with boranes.
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