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A New Route to Iron‐Sulfur Clusters: Synthesis and Structure of [(C 2 H 5 ) 4 N] 2 Fe 6 S 6 I 6
Author(s) -
Saak Wolfgang,
Henkel Gerald,
Pohl Siegfried
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198401502
Subject(s) - stoichiometry , cluster (spacecraft) , sulfur , crystallography , iodine , chemistry , materials science , organic chemistry , computer science , programming language
The preparation of the iodine‐substituted FeS cluster [Fe 6 S 6 I 6 ] 2⊖ 1 was carried out by heating stoichiometric amounts of Fe, S 8 , I 2 , and I ⊖ . 1 contains two Fe 3 S 3 six‐membered rings linked via six FeS bonds. The known clusters [Fe 2 S 2 I 4 ] 2⊖ and [Fe 4 S 4 I 4 ] 2⊖ were obtained analogously.
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