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Sulfur Imide as bisdihapto ‐Bridging Ligand in the Complex Fe 2 (CO) 6 (HNS)
Author(s) -
Herberhold Max,
Bühlmeyer Wolfgang
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198400801
Subject(s) - imide , sulfur , bridging (networking) , ligand (biochemistry) , chemistry , inorganic chemistry , materials science , polymer chemistry , computer science , organic chemistry , receptor , biochemistry , computer network
The stabilization of sulfur imide (HNS) , which is not known in the free state, was accomplished for the first time by coordination to iron centres. In the complex 1 , HNS functions as a six‐electron ligand.