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Hydrozirconation of Nitriles: Proof of a Linear Heteroallene Structure in (Benzylideneamido)zirconocene Chloride
Author(s) -
Erker Gerhard,
Frömberg Wolfgang,
Atwood Jerry L.,
Hunter William E.
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198400681
Subject(s) - derivative (finance) , similarity (geometry) , ion , chemistry , chloride , ground state , computational chemistry , organic chemistry , computer science , physics , atomic physics , artificial intelligence , financial economics , economics , image (mathematics)
The structural similarity of carbenium ions 1 and the neutral zirconocene derivative 2 in the ground state is surprising only at first glance; the isolobal model gives an explanation. 2 , R. Ph, contains the shortest ZrN bond known so far in molecular Zr compounds (2.013 Å).