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Novel Structures Containing Germanium( II ): Germanocene Dimeric Tricarbonyl(di‐ tert ‐butoxygermylene)nickel(0)
Author(s) -
Grenz Mario,
Hahn Ekkehardt,
du Mont WolfWalther,
Pickardt Joachim
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198400611
Subject(s) - germanium , nickel , monomer , germanium compounds , chemistry , materials science , polymer chemistry , crystallography , organic chemistry , polymer , silicon
The X‐ray structure analysis of germanocene 1 —prepared for the first time in pure form from NaC 5 H 5 and GeCl 2 ·dioxane, and stable for weeks at −30°C—shows that it is present as the monomer. 1 is an excellent educt for the synthesis of Ge II compounds, e.g., alcoholysis leads to 2 .
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