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1,3‐Bis(tri‐ tert ‐butylsilyl)triazene
Author(s) -
Wiberg Nils,
Fischer Gerd,
Karampatses Petros
Publication year - 1984
Publication title -
angewandte chemie international edition in english
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 5.831
H-Index - 550
eISSN - 1521-3773
pISSN - 0570-0833
DOI - 10.1002/anie.198400591
Subject(s) - triazene , silylation , derivative (finance) , chemistry , medicinal chemistry , atom (system on chip) , stereochemistry , organic chemistry , computer science , financial economics , economics , catalysis , embedded system
The first silyl derivative of triazene is unusually stable (up to 150°C!) due to the two extraordinarily bulky tri‐ tert ‐butylsilyl substituents. It follows from the 1 H‐NMR spectrum that the N ‐bonded H atom migrates at 55°C.
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