Heterogeneous Hydrogenation of Organic Halogen Compounds by Carrier‐Supported Organotin Hydrides | Zendy

Schumann Herbert | Zendy; Pachaly Bernd | Zendy

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Heterogeneous Hydrogenation of Organic Halogen Compounds by Carrier‐Supported Organotin Hydrides

Author(s) -

Schumann Herbert,

Pachaly Bernd

Publication year - 1981

Publication title -

angewandte chemie international edition in english

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 5.831

H-Index - 550

eISSN - 1521-3773

pISSN - 0570-0833

DOI - 10.1002/anie.198110431

Subject(s) - reagent , tin , hydride , halogen , chemistry , reducing agent , inorganic chemistry , combinatorial chemistry , materials science , organic chemistry , metal , alkyl

Organotin hydrides supported on inorganic carriers such as Al 2 O 3 or SiO 2 exhibit high stability and regenerability . Such reagents, which are effective reducing agents, have now been prepared for the first time. With the Al 2 O 3 ‐supported tin hydride reagent (1) , it is possible to reduce 1,1‐dichloro‐2,2‐di‐phenylcyclopropane quantitatively to 1,1‐diphenylcyclopropane.

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